A single drop is very unlikely to cause any serious toxicity or harm. You might notice some mild stomach upset, which is completely normal and should pass. For peace of mind, just keep him hydrated and monitor him closely. If he develops any coughing, wheezing, vomiting, or unusual sleepiness, please seek immediate medical care or contact poison control.
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Will it cause any problems if my 15-month-old baby accidentally swallowed a Vicks chocolate cough drop?